Bleach: The Substitute - Volume 3

Ichigo and Rukia continue their work as Soul Reapers, protecting spirits and the living. But they are not the only ones with the power to defeat the evil Hollows. A rival called a Quincy appears with fearsome powers of his own - and a grudge against all Soul Reapers. When he issues a Hollow-battling challenge to Ichigo, it could destroy the world of the living.